Открытый доступ Открытый доступ  Ограниченный доступ Доступ для подписчиков

Альтернативная кинетическая модель роста боридных слоев на стали AISI 316

М. Кеддам, П. Журчи

Аннотация


Предложена альтернативная кинетическая модель для анализа роста боридов железа на поверхности стали AISI 316 в интервале температур 1123 - 1273 К. Разработанный подход основан на классических законах Фика с учетом влияния инкубационного периода на процесс формирования боридных слоев. Рассчитана энергия активации бора для FeB и Fe2B и проведено ее сравнение с литературными данными. Выполнена экспериментальная проверка модели для борирования при 1243 К в течение 3 ч и 5 ч. Сравнение экспериментальных значений толщины слоев с прогнозируемыми по альтернативной диффузионной модели и интегральному методу показало их хорошее соответствие.

Ключевые слова


boronizing; iron borides; alternative model; kinetics; activation energy

Полный текст:

PDF

Литература


Kulka M. Trends in thermochemical techniques of boriding // Engineering Materials. Current Trends in Boriding. Cham, Switzerland: Springer, 2019. P. 17 - 98.

Bayзa S. U., Bican O., Yamanel B. et al. The effect of solid boriding time on the structure, hardness and corrosion properties of AISI 5140 steel // Prot. Met. Phys. Chem. Surf. 2020. V. 56. P. 591 - 597.

Ipek M., Celebi Efe G., Ozbek I. et al. Investigation of boronizing kinetics of AISI 51100 steel // Journal of Materials Engineering and Performance. 2012. V. 21. P. 733 - 738.

Martini C., Palombarini G., Poli G., Prandstraller D. Sliding and abrasive wear behaviour of boride coatings // Wear. 2004. V. 256. P. 608 - 613.

Karakaş M. S., Gьnen A., Kanca E., Yilmaz E. Boride layer growth kinetics of AISI H13 steel borided with nano-sized powders // Arch. Metall. Mater. 2018. V. 63. P. 159 - 165.

Kulka M., Makuch N., Pertekand A., Maldzinski L. Simulation of the growth kinetics of boride layers formed on Fe during gas boriding in H2-BCl3 atmosphere // Journal of Solid State Chemistry. 2014. V. 199. P. 196 - 203.

Keddam M., Kulka M., Makuch N. et al. A kinetic model for estimating the boron activation energies in the FeB and Fe2B layers during the gas-boriding of Armco iron: Effect of boride incubation times // Appl. Surf. Sci. 2014. V. 298. P. 155 - 163.

Simonenko A. N., Shestakov V. A., Poboinya V. N. Liquid boriding in induction salt baths // Met. Sci. Heat Treat. 1982. V. 24. P. 360 - 361.

Campos I., Torres R., Bautista O. et al. Effect of boron paste thickness on the growth kinetics of polyphase boride coatings during the boriding process // Applied Surface Science. 2006. V. 252. P. 2396 - 2403.

Elias-Espinosa M., Ortiz-Domнnguez M., Keddam M. et al. Boriding kinetics and mechanical behavior of AISI O1 steel // Surface Engineering. 2015. V. 31. P. 588 - 597.

Anthymidis K. G., Stergioudis E., Tsipas D. N. Boriding in a fluidized bed reactor // Materials Letters. 2001. V. 51. P. 156 - 160.

Rodrıguez Cabeo E., Laudien G., Biemer S. et al. Plasma-assisted boriding of industrial components in a pulsed d.c. glow discharge // Surface and Coatings Technology. 1999. V. 116 - 119. P. 229 - 233.

Gunes I., Taktak S., Bindal C. et al. Investigation of diffusion kinetics of plasma paste borided AISI 8620 steel using a mixture of B2O3 paste and B4C/SiC // Sadhana. 2013. V. 38. P. 513 - 526.

Keddam M., Chegroune R., Kulka M. et al. Characterization, tribological and mechanical properties of plasma paste borided AISI 316 steel // Transactions of the Indian Institute of Metals. 2018. V. 71. P. 79 - 90.

Keddam M., Chentouf S. M. A diffusion model for describing the bilayer growth (FeB/Fe2B) during the iron powder-pack boriding // Applied Surface Science. 2005. V. 252. P. 393 - 399.

Brakman C. M., Gommers A. W. J., Mittemeijer E. J. Boriding of Fe and Fe - C, Fe - Cr, and Fe - Ni alloys; Boride- layer growth kinetics // Journal of Materials Research. 1989. V. 4. P. 1354 - 1370.

Mebarek B., Keddam M., Aboshighiba H. LS-SVM approach for modeling the growth kinetics of FeB and Fe2B layers formed on Armco iron // Ingйnierie des systems d'information. 2018. V. 23. P. 29 - 41.

Campos-Silva I., Ortiz-Dominguez M., Tapia-Quintero C. et al. Kinetics and boron diffusion in the FeB/Fe2B layers formed at the surface of borided high-alloy steel // J. Mater. Eng. Perform. 2012. V. 21. P. 1714 - 1723.

Keddam M., Kulka M. A kinetic model for the boriding kinetics of AISI D2 steel during the diffusion annealing process // Protection of Metals and Physical Chemistry of Surfaces. 2018. V. 54. P. 282 - 290.

Campos I., Torres R., Ramirez G. et al. Growth kinetics of iron boride layers: Dimensional analysis // Applied Surface Science. 2006. V. 252. P. 8662 - 8667.

Campos-Silva I., Ortiz-Domнnguez M., Bravo-Bбrcenas O. et al. Formation and kinetics of FeB/Fe2B layers and diffusion zone at the surface of AISI 316 borided steels // Surface and Coatings Technology. 2010. V. 205. P. 403 - 412.

Campos-Silva I., Ortiz-Domнnguez M., Lуpez-Perrusquia N. et al. Determination of boron diffusion coefficients in borided tool steels // Defect and Diffusion Forum. 2009. V. 283 - 286. P. 681 - 686.

Keddam M., Kulka M. Boriding kinetics of AISI D2 steel by using two different approaches // Metal Science and Heat Treatment. 2020. V. 61. P. 756 - 763.

Keddam M., Kulka M. Simulation of the growth kinetics of FeB and Fe2B layers on AISI D2 steel by the integral method // Physics of Metals and Metallography. 2018. V. 119. P. 842 - 851.

Yu L. G., Chen X. J., Khor A. K., Sundararajan G. FeB/Fe2B phase transformation during SPS pack-boriding: Boride layer growth kinetics // Acta Mater. 2005. V. 53. P. 2361 - 2368.

Okamoto H. B - Fe (boron-iron) // J. Phase Equilibria and Diff. 2004. V. 25. P. 297 - 298.

Yu L. G., Khor K. A., Sundararajan G. Boriding of mild steel using the spark plasma sintering (SPS) technique // Surface and Coatings Technology. 2002. V. 157. P. 226 - 230.

Kartal G., Eryilmaz O. L., Krumdick G. et al. Kinetics of electrochemical boriding of low carbon steel // Applied Surface Science. 2011. V. 257. P. 6928 - 6934.

Sen S., Sen U., Bindal C. An approach to kinetic study of borided steels // Surface and Coatings Technology. 2005. V. 191. P. 274 - 285.

Genel K., Ozbek I., Bindal C. Kinetics of boriding of AISI W1 steel // Materials Science and Engineering A. 2003. V. 347. P. 311 - 314.

Genel K. Boriding kinetics of H13 steel // Vacuum. 2006. V. 80. P. 451 - 457.

Зelik A. G. Investigation of the diffusion rate of boron atom in AISI D3 steel // Prot. Met. Phys. Chem. Surf. 2020. V. 56. P. 780 - 784.

Keddam M., Kulka M. Modeling of the kinetics of boron diffusion in dehydrated paste pack-borided AISI M2 steel based on two mathematical approaches // Materials and Performance Characterization. 2020. V. 9. P. 303 - 314.

Ozdemir O., Omar M. A., Usta M. et al. An investigation on boriding kinetics of AISI 316 stainless steel // Vacuum. 2008. V. 83. P. 175 - 179.

Martini C., Palombarini G., Carbucicchio M. Mechanism of thermochemical growth of iron borides on iron // Journal of Materials Science. 2004. V. 39. P. 933 - 937.

Press W. H., Flannery B. P., Teukolsky S. A. Numerical recipes in Pascal: The art of scientific computing. Cambridge: Cambridge University Press, 1989. 759 p.




DOI: https://doi.org/10.30906/mitom.2021.8.29-35


© Издательский дом «Фолиум», 1998–2025